Patent attributes
A method includes predicting a composition of calcium-magnesium-aluminum-silicate (CMAS) to be encountered by a high temperature mechanical system during use of the high temperature mechanical system. The method further includes selecting a composition of a CMAS-resistant barrier coating layer based at least in part on the predicted composition of CMAS. The CMAS-resistant barrier coating layer includes a base composition and at least one secondary oxide selected based on the predicted composition of CMAS. The at least one secondary oxide includes at least one of an oxide of a divalent element, an oxide of a trivalent element, or an oxide of a tetravalent element. The CMAS-resistant barrier coating layer comprises greater than 0 mol. % and less than about 7 mol. % of the at least one secondary oxide.