A frunk latch emergency opening structure includes: a base configured to be fixed to a vehicle body; a pawl provided on the base so as to be rotatable; a first cable connected to one end of the pawl and configured such that tension is applied to the first cable by operating a vehicle inside handle; an emergency lever configured to be rotatable in an interlocking manner with the pawl at one end of the emergency lever; a second cable connected to another end of the emergency lever and configured such that tension is applied to the second cable by operating a frunk inside handle; and a safety hook configured to be coupled to the base so as to be rotatable and to move due to operation of a front outside lever.