Disclosed herein are pristine graphene sheets with columns formed of fullerene nanotubes between the graphene sheets for use as body armor, semiconductor, battery anode, solar panels, heat sinks, structural concrete members, structural steel members, precast concrete structural members, bridges, highways, streets, skyscrapers, sidewalks, foundations, dams, industrial plants, canals, airports, structural composites, aircraft, military equipment, and civil infrastructure.