A positive electrode including a plurality of electroactive particles defining an electroactive layer is provided. A first lithium-containing coating is disposed on one or more surfaces of the electroactive layer. The first lithium-containing coating covers between about 30% and about 50% of a total exposed surface area of the electroactive layer. A second lithium-containing coating encompasses at least one electroactive particle of the plurality of electroactive particles. The second lithium-containing coating covers between about 95% and about 100% of the at least one electroactive particle. The first and second lithium-containing coatings each have a thickness between about 0.2 nm and about 5 nm. The positive electrode further includes an electrolyte additive that aids in the formation of a first passivation layer on exposed surfaces of the first lithium-containing coating, and a second passivation layer on exposed surfaces of the second lithium-containing coating.