The invention discloses novel series of silicone esters, which are useful as antioxidants on skin. The products are produced using for a variety of hydroxyl containing actives such as vitamin A (retinol), vitamin A-2, and vitamin E. Compounds of the invention are prepared by the esterification of (a) a specific silicone methyl ester and (c) a hydroxyl functional active. The esters of the present invention allow for the formulation of personal care products in which the “active” can be formulated into a variety of solvents without the loss of activity.