A chair adjustable device includes a base with which a seat frame and a backrest frame are respectively and pivotably connected. A positioning mechanism is connected to the base and includes an operation handle which is able to shift a transmission frame and a positioning plate is movably connected to the transmission frame and biased by a spring, so that the positioning plate can be movably engaged with one of notches defined in a positioning member on the seat frame. The seat frame and the backrest frame are connected by a connection member so that the chair can be adjusted its tilt angle by operating the operation handle.