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US Patent 7649101 Process for selective oxidation of olefins to epoxides

Patent 7649101 was granted and assigned to University of Kansas on January, 2010 by the United States Patent and Trademark Office.

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Patent abstract

A process for the selective oxidation of olefins to epoxides comprising the step of contacting the olefin (propylene) with an oxidant (hydrogen peroxide) in the presence of a Lewis acid oxidation catalyst (MTO), organic base (pyridine or its N-oxide), in a solvent system comprising an organic water-miscible solvent (methanol); and adding a pressurizing gas (nitrogen) to increase the pressure, whereby olefin is further dissolved in organic solvent system to increase the selectivity and yield of the desired epoxide (propylene oxide).

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