Compositions comprising an asymmetric disiloxane surfactant composition comprising a silicone composition comprising a silicone having the formula:MM′where M or M′ comprises an alkylpolyalkyleneoxide bearing substituent selected from the group consisting of:R13(C2H4O)a(C3H6O)b(C4H8O)cR14 andR12SiR5R6(R13(C2H4O)a(C3H6O)b(C4H8O)cR14)that exhibit resistance to hydrolysis over a wide pH range.