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US Patent 7745544 Catalytic epoxidation and hydroxylation of olefin/diene copolymers

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Patent
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Patent Jurisdiction
United States Patent and Trademark Office
United States Patent and Trademark Office
Patent Number
7745544
Date of Patent
June 29, 2010
Patent Application Number
11606738
Date Filed
November 30, 2006
Patent Primary Examiner
‌
Ling Siu Choi
Patent abstract

Disclosed are processes for preparing an epoxidized and/or hydroxylated α-olefin/diene copolymer materials such as ethylene/dicyclopentadiene. These processes comprise contacting in a reaction medium a) a copolymeric precursor component with b) a hydrogen peroxide oxidizing agent, in the presence of alkyl-trioxorhenium-based catalyst, under certain reaction conditions. The copolymeric precursor component comprises copolymers of α-olefins and dienes with these copolymers containing at least one double bond in each diene-derived comonomer. The reaction medium is maintained under reaction conditions which promote formation of oxirane rings at, and/or diol formation across, the sites of the diene-derived co-monomer double bonds in the copolymeric precursor material.

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