Disclosed is an oxygen evolution electrode for formation of only oxygen without formation of chlorine at anode in the performance and the durability of the anode is so high that they are, even in strong acid, at the same level as that in neutral solution. The electrode is prepared by anodic deposition of multiple oxide consisting of Mn—Mo—Sn, Mo—W—Sn or Mn—Mo—W—Sn on an IrO2-coated titanium substrate. The multiple oxide are composed of Mn as the main component, 0.1-3 cationic % of Sn and 0.2-20 cationic % of Mo and/or W.