A film forming composition with spreading properties derived from an aqueous emulsion comprising (I) colloidal silica core/silicone shell particles consisting of (a) 90 wt % to 10 wt % cores of colloidal silica and (b) 10 wt % to 90 wt % shells of polyorganosiloxane; (II) a polyalkyleneoxide modified trisiloxane; (III) an emulsifier package consisting of at least one anionic surfactant, and (IV) the salt of an acidic polymerization catalyst. The composition may include optional ingredients useful in Personal Care, Hair Care, Skin Care, Agricultural, and Home Care applications.