An analog-to-digital converting system includes at least one first main analog-to-digital converting unit, at least one second main analog-to-digital converting unit, at least one auxiliary analog-to-digital converting unit, and a calibration unit. Each first main analog-to-digital converting unit is located on a first channel. The first channel includes sample period. Each first main analog-to-digital converting unit receives a first sampling value. Each first sampling value includes a first sample clock. An analog-to-digital converting method calibrates timing-skew of the analog-to-digital converters by delaying a time difference on the sampling value.