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US Patent 9908840 Reactions of aromatic substrates with base-activated hydrosilanes-silylations and reductive cleavage

Patent 9908840 was granted and assigned to California Institute of Technology on March, 2018 by the United States Patent and Trademark Office.

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Patent abstract

The present invention describes chemical systems and methods for reducing C—O, C—N, and C—S bonds, said system comprising a mixture of (a) at least one organosilane and (b) at least one strong base, said system being substantially free of a transition-metal compound, and said system optionally comprising at least one molecular hydrogen donor compound, molecular hydrogen, or both.

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